Legal Question in Immigration Law in Georgia

You need to be more specific about your husband's status in USA (visa, if any), his location (USA or Mexico), etc - in order to get a more or less picture of his eligibility to apply for a Green Card (permanent residency).

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It depends on how your husband entered the US and if any immigration petition was ever filed for him in the past.

Assuming he entered illegally and never had anything filed for him in the past, he'll likely need to undergo the immigration waiver process detailed here:

http://www.msclaw.com/immigration-waivers.html